Angelina Jolie Confesses Why Marriage To Brad Pitt Ended

The Big One

Image: Andrew Kent/Getty Images

Little was heard from Jolie after that. However, that all changed in 2005. That was, of course, the year in which she landed the role in Mr. and Mrs. Smith. During filming, rumors started to emerge that she had become involved with Brad Pitt who at that time was married to Friends star Jennifer Aniston.

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